Water-absorbing resin and process for producing same

ABSTRACT

A process for producing a water-absorbing resin, which comprises polymerizing (D) an aqueous solution comprising (A) at least one monomer component selected from the group consisting of an unsaturated carboxylic acid and salts thereof; (B) a compound having two or more unsaturated groups in a molecule; and (C) a compound having two or more functional groups which are capable of reacting with carboxyl groups in a molecule, the polymerization being conducted in such a manner that the following conditions (a) to (c) are simultaneously satisfied: (a) the molar ratio (B)/(C) being in the range of from 2x10-3 to 300, (b) the polymerization being initiated by a redox polymerization initiator, and (c) the maximum reaction temperature being in the range of from 60° to 100° C., and a water-absorbing resin having a degree of reduction in absorption magnification of from 1 to 16, and n absorption magnification under pressure of from 20 to 40.

FIELD OF THE INVENTION

The present invention relates to a process for producing awater-absorbing resin, and more specifically, relates to a process forproducing a water-absorbing resin that is excellent in absorbingproperties and has a reduced amount of water-soluble content. Thepresent invention also relates to a water-absorbing resin, and morespecifically it relates to a water-absorbing resin that has a reducedamount of water-soluble content, a high salt resistance, and excellentabsorbing properties under pressure. The present invention also relatesto a water-absorbing article, and more specifically it relates to awater-absorbing article containing a water-absorbing resin that has areduced amount of water-soluble content, a high salt resistance, andexcellent absorbing properties under pressure.

BACKGROUND OF THE INVENTION

Water-absorbing resins have been used in various absorbing articles.Such article include diapers, sanitary goods, soil water-retainingagent, freshness-maintaining agents, dew condensation preventing agents,sealing materials, etc.

Various water-absorbing resins and processes for producing them havebeen proposed. Examples of the known water-absorbing resins include ahydrolyzed product of a starch-acrylonitrile graft copolymer (asdescribed in JP-B-49-43395), a partially neutralized material of astarch-acrylic acid graft copolymer (as described in JP-B-53-46199), asaponified material of a acrylic acid ester-vinyl acetate copolymer (asdescribed in JP-B-53-13495), a crosslinked material of a partiallyneutralized acrylic acid (as described in JP-B-58-35605), a modifiedmaterial of a crosslinked polyvinyl alcohol (as described inJP-A-54-20093), etc. (The term “JP-B” as used herein means an examinedJapanese patent publication, and the term “JP-A” as used herein means anunexamined published Japanese patent application.)

The above-described conventional water-absorbing resins contain acertain amount of water-soluble content. The presence of thewater-soluble content sometimes is not desirable in the aspect of boththe performance and the safety of the water-absorbing resin. Forexample, when the water-absorbing resin is in contact with a liquid tobe absorbed to form a hydrogel structure whereby the water-solublecontent is extracted into the liquid to be absorbed, not only theabsorbing properties of the resin are reduced in proportion to theextracted water-soluble content, but also deterioration of thewater-absorbing resin is accelerated. When a large amount of thewater-soluble content is in contact with a human body, etc., such awater-soluble content sometimes is not desirable from the viewpoint ofsafety as it gives unpleasant slimy feeling, etc.

Processes for producing water-absorbing resins having a small amount ofwater-soluble content have been proposed. Examples of such processesinclude a process comprising polymerizing a monomer containing both apolymerizable unsaturated group and a free acid group, followed byneutralization (as described in JP-A-62-54751), a process comprisingpolymerizing a low-neutralized monomer, followed by neutralization (asdescribed in JP-A-1-144404), a process comprising irradiating awater-absorbing resin with an ultraviolet ray in the presence of aradical scavenger (as described in JP-A-4-120112), a process comprisingadding a reducing substance and a radical scavenger to a water-absorbingresin (as described in JP-A-4-120111), etc.

The above-described processes each includes a new unit operation whichis required in production steps. For example, in the processes ofJP-A-62-54751 and JP-A-4-144404, a neutralization step is required afterthe polymerization. In the processes of JP-A-4-120112 and JP-A-4-120111,a step for mixing an additive with the water-absorbing resin and a stepfor irradiating the water-absorbing resin with an ultraviolet ray arerequired. In the step for neutralization of the water-absorbing resinafter polymerization, and the step for mixing additives with thewater-absorbing resin after polymerization, a uniform neutralization ormixing is difficult and may cause a decrease in the productivity.

It is generally known that the amount of water-soluble content can bereduced by increasing the amount of a crosslinking agent used. However,as a result of the use of an increased amount of a crosslinking agent,the absorbing properties of the water-absorbing resin decreases.

Water-absorbing resins having a small amount of water-soluble contenthave been known. For example, in a process for producing awater-absorbing resin by adiabatic polymerization (as described inJP-B-1-31531), a polymer gel is treated with water and a methanolsolution. In this production process, a water/methanol treatment isrequired and therefore the productivity decreases. Further, it isprobable that methanol remains in the resulting resin and, hence, theprocess is not desirable from the standpoint of safety.

Water-absorbing resins sometimes required to have salt resistance. Forexample, the absorbing properties change depending on the kind ofsolutions to be absorbed and depending on the lapse of time.

The water-absorbing resin containing an electrolytic structure such asthe partially neutralized acrylic acid described above generally haspoor salt resistance. If such a water-absorbing resin is used as adiaper, the absorbing properties are changed due to the change inconcentration of salts from electrolytes in urine and the lapse of time,resulting in fluctuation of product quality.

It is known that nonionic water-absorbing resins and sulfonicgroup-containing water-absorbing resins are excellent in absorbingproperties to electrolytic solutions. Examples thereof include thewater-absorbing resin contained in the water-swellable waterproofingmaterial (as described in JP-A-62-259846), the water-absorbing resincontained in the waterproofing material for cables (as described inJP-A-4-363383), and the waterproofing material for optical and electriccables (as described in JP-B-5-4764). However, these water-absorbingresins have low gel strength, resulting in deteriorated absorbingproperties under pressure.

Water-absorbing resins having high absorbing properties under pressurehave been known. For example, a water-absorbing resin having highabsorbing properties under pressure is used in the absorbing articlecontaining hydrogel having high absorption capability under pressure (asdescribed in U.S. Pat. No. 5,147,343).

Processes for producing a water-absorbing resin having high absorbingproperties under pressure also have been known. Examples thereof includea process for producing powdery polymer with selecting surfactant (asdescribed in French Patent 8,611,742), a process for producing awater-absorbing resin by a high-concentration polymerization (asdescribed in JP-A-63-275607), a process for producing a water-absorbingresin by forced heating (as described in JP-A-63-275608), and a processfor producing water-absorbing resin by mixing a second crosslinkingagent, followed by subjecting heating treatment (as described inJP-A-6-184320). However, these water-absorbing resins having highabsorbing properties under pressure do not have high salt resistance.

The present invention is directed to solution of the above-describedproblems.

SUMMARY OF THE INVENTION

An object of the present invention is to provide a process for producinga water-absorbing resin having satisfactory absorbing properties andhaving a small amount of water-soluble content.

Another object of the present invention is to provide a process forproducing a water-absorbing resin having a markedly small amount ofwater-soluble content and high safety.

Further object of the present invention is to provide an expedient andhighly productive process for producing a water-absorbing resin havingsatisfactory absorbing properties and a small amount of water-solublecontent.

Still further object of the present invention is to provide awater-absorbing resin having a small amount of water-soluble content,high salt resistance, and excellent absorbing properties under pressure.

Still further object of the present invention is to provide awater-absorbing article containing a water-absorbing resin having asmall amount of water-soluble content, high salt resistance, andexcellent absorbing properties under pressure.

Still further object of the present invention is to provide awater-absorbing article having a reduced change in absorbing propertiesafter absorption, which has been a problem in water-absorbing articlescontaining conventional water-absorbing resins.

The present invention relates to a process for producing awater-absorbing resin, which comprises polymerizing (D) an aqueoussolution comprising (A) at least one monomer component selected from thegroup consisting of an unsaturated carboxylic acid and salts thereof;(B) a compound having two or more unsaturated groups in a molecule; and(C) a compound having two or more functional groups which are capable ofreacting with carboxyl groups in a molecule, the polymerization beingconducted in such a manner that the following conditions (a) to (c) aresimultaneously satisfied:

(a) the molar ratio (B)/(C) being in the range of from 2×10⁻³ to 300,

(b) the polymerization being initiated by a redox polymerizationinitiator, and

(c) the maximum reaction temperature being in the range of from 60° to100° C.

In the process according to the present invention, it is preferred thatthe following conditions (d) to (f) are simultaneously satisfied:

(d) the molar ratio (B)/(C) being in the range of from 0.01 to 30,

(e) the molar ratio (B)/(A) being in the range of from 1×10⁻⁴ to 3×10⁻³,and

(f) the molar ratio (C)/(A) being in the range of from 1×10⁻⁴ to 1×10⁻².

It is also preferred that the process according to the present inventionfurther comprises drying after the polymerization.

The present invention also relates to a water-absorbing resin having adegree of reduction in absorption magnification of from 1 to 16, and anabsorption magnification under pressure of from 20 to 40.

The present invention further relates to a water-absorbing articlecomprising the above water-absorbing resins, or the abovewater-absorbing resins which are produced by the above processes.

BRIEF DESCRIPTION OF DRAWING

FIG. 1 shows a schematic cross section of an apparatus for measuring anabsorption magnification under pressure of a water-absorbing resin.

DETAILED DESCRIPTION OF THE INVENTION

The “degree of reduction in absorption magnification” as used hereinmeans the value measured according to the following method:

E (g) (about 0.2 g) of a water-absorbing resin to be measured is placeduniformly in a bag made of nonwoven cloth (40×150 mm), and immersed inan artificial urine I (an aqueous solution containing 1.9 wt % of urea,0.8 wt % of sodium chloride, 0.1 wt % of magnesium sulfate, and 0.1 wt %of calcium chloride) at 25° C. for a prescribed period of time. Afterthe bag is taken out from the artificial urine I, the artificial urine Iis naturally drained for 5 second in the air and for further 10 secondson 24 sheets of toilet paper each having a rectangular form of 5.0cm×5.7 cm, and the weight (F (g)) of the bag containing thewater-absorbing resin is measured. The same procedures as above areconducted by using the same nonwoven cloth bag but using nowater-absorbing resin, and the weight (G (g)) of the bag is measured.The absorption magnification at the prescribed period of time iscalculated by the following equation:

Absorption magnification (g/g)=(F(g)−G(g))/E(g)

The degree of reduction in absorption magnification is calculated by thefollowing equation:

Degree of reduction in absorption magnification (g/g)=Absorptionmagnification after 10 minutes (g/g)−Absorption magnification after 3hours (g/g)

The “absorption magnification under pressure” as used herein means avalue measured according to the following method by using an apparatusshown in FIG. 1:

An artificial urine II 3 (an aqueous solution containing 2.0 0.20 wt %of potassium chloride, 2.0 0.20 wt % of anhydrous sodium sulfate, 0.850.085 wt % of ammonium dihydrogenphosphate, 0.15 0.015 wt % ofdiammonium hydrogenphosphate, 0.25 0.025 wt % of potassiumcalciumchloride dihydrate, and 0.5 0.05 wt % of magnesium chloride hexahydrate)at 25° C. is placed in a vessel 4 equipped with an air inlet pipe 2,which is placed on a balance 1. The interior of the vessel 4 isconnected to a reverse funnel 6 through a connecting pipe 5. A glassfilter 7 is fixed at the top of the reverse funnel 6, while the top endof the glass filter 7 and the bottom end 8 of the air inlet pipe 2 areplaced at the same height. A cylinder 13 (inner diameter: 6.0 cm) havinga stainless steel mesh bottom 12 containing a water-absorbing absorbingresin 11 (0.9 g) having placed thereon a weight 10 (pressure: 0.70 psi)is placed on the glass filter 7. The weight of the artificial urine II 3that are absorbed by the water-absorbing resin 11 after 60 minutes isdivided by 0.9 to result absorption magnification under pressure (g/g).

The present invention relates to a process for producing awater-absorbing resin. Examples of the unsaturated carboxylic acid usedas the monomer component (A) in the present invention includes(meth)acrylic acid, crotonic acid, itaconic acid, maleic acid, fumaricacid, citraconic acid, etc., and one or more of these acids can be used.The use of acrylic acid is more preferred.

The term “(meth)acrylic” and the like used herein means “acrylic ormethacrylic” and the like.

Examples of the salt of unsaturated carboxylic acid used as the monomercomponent (A) in the present invention includes an alkali metal salt, anammonium salt and a substituted ammonium salt, etc., and one or more ofthese salts can be used. The use of a sodium salt of acrylic acid as asalt of unsaturated carboxylic acid salt is more preferred.

The above unsaturated carboxylic acid and salts thereof may be usedsingly or in combination of two or more of them.

There is no particular limitation in the amount ratio between theunsaturated carboxylic acid and the salt of unsaturated carboxylic acidfor the monomer component (A), but it is preferred that the unsaturatedcarboxylic acid is neutralized in the range of from 30 to 90 mol%, andparticularly preferably from 60 to 80 mol%.

The compound (B) having two or more unsaturated groups in a moleculeused in the present invention is not particularly limited as long as ithas two or more unsaturated groups in a molecule. Examples thereofinclude ethylene glycol di(meth)acrylate, diethylene glycoldi(meth)acrylate, triethylene glycol di(meth)acrylate, propylene glycoldi(meth)acrylate, polyethylene glycol di(meth)acrylate,trimethylolpropane di(meth)acrylate, trimethylolpropanetri(meth)acrylate, pentaerythritol di(meth)acrylate, pentaerythritoltri(meth)acrylate, pentaerythritol tetra(meth)acrylate,N,N-methylenebis(meth)acrylamide, triallyl isocyanurate.trimethylolpropane di(meth)allyl ether, triallylamine,tetraallyloxyethane, and glycerolpropoxy triacrylate. One or more ofthese compounds can be used by appropriately selecting the compounds bytaking solubility and reactivity of the compounds into consideration. Itis preferred to use polyethylene glycol di(meth)acrylate ortrimethylolpropane tri(meth)acrylate as the compound (B).

The compound (B) having two or more unsaturated groups in a moleculeused in the present invention is preferably used at a molar ratio(B)/(A) in the range of from 1×10⁻⁴ to 3×10⁻³.

An example of the process for producing a water-absorbing resin withhigh productivity is a process for polymerization while finely dividingthe hydrogel (as described in JP-B-2-19122). When the molar ratio(B)/(A) is below 1×10⁻⁴ the strength of a hydrogel at an early stage ofthe polymerization, specifically, at a stage until reaching the maximumreaction temperature, sometimes may not be sufficient to finely dividethe hydrogel, even if these compounds are used together with thecompound (C). When the molar ratio (B)/(A) is higher than 3×10⁻³, theabsorbing properties of the resulting resin may sometimes decreases toan undesirable level. The molar ratio (B)/(A) is more preferably in therange of from 5×10⁻⁴ to 2.5×10⁻³.

Examples of the compound (C) having two or more functional groupscapable of reacting with carboxyl groups in a molecule include compoundshaving two or more epoxyl groups in a molecule such as ethylene glycoldiglycidyl ether, polyethylene glycol diglycidyl ether, polypropyleneglycol diglycidyl ether, neopentyl glycol diglycidyl ether,1,6-hexanediol diglycidyl ether, glycerin triglycidyl ether andtrimethylolpropane triglycidyl ether; compounds having two or morehalogen groups and epoxyl groups in a molecule such as epichlorohydrinand α-methylepichlorohydrin; compounds having two or more isocyanategroup such as 2,4-trilenediisocyanate and hexamethylene diisocyanate;compounds having two or more aziridine groups in a molecule such astrimethylolpropanetri(3-(1-aziridinyl)propionate) anddiphenylmethane-bis-4,4′-N,N′-diethyleneurea; and compounds having twoor more aziridinium salts in a molecule such as polyamide polyamineepihalohydrine adducts. These compounds can be used singly or incombination of two or more of them, with the solubility and thereactivity being taken into consideration. Among these compounds, thecompound having two or more epoxyl groups in a molecule is particularlypreferred as the compound (C).

The compound (C) having two or more functional groups in a moleculewhich is capable of reacting with carboxyl groups is preferably used ata molar ratio (C)/(A) in the range of from 5×10⁻⁵ to 1×10⁻².

When the molar ratio (C)/(A) is below 5×10⁻⁵, the resulting effectsometimes may be unsatisfactory, even when the compound (B) is usedtogether. When the ratio is higher than 1×10⁻², the absorptionproperties of the produced water-absorbing resin tend to become low andthus may not be suitable for use in industry. The molar ratio (C)/(A) ismore preferably in the range of from 1×10⁻⁴ to 1×10⁻².

It is necessary that the molar ratio of the compound (B) to the compound(C), (B)/(C), used in the present invention is in the range of from2×10⁻³ to 300.

When the molar ratio (B)/(C) is below 2×10⁻³, the strength of a hydrogelat an early stage of the polymerization, specifically, until reachingthe maximum reaction temperature may be insufficient to finely dividethe hydrogel. When the molar ratio (B)/(C) is more than 300, an effectobtainable by using the compound (C) and the compound (B) together maynot be exhibited. The molar ratio (B)/(C) is preferably in the range offrom 0.01 to 100, more preferably in the range of from 0.01 to 30.

In the present invention, it is necessary to use a redox polymerizationinitiator. If the redox polymerization initiator is not used, themaximum reaction temperature becomes too high since the polymerizationreaction is difficult to control, and the amount of a water-solublecontent in the resulting water-absorbing resin increases. Also, anintroduction time until the reaction starts becomes too long wherebyproductivity may decrease.

Oxidizing agents of the redox polymerization initiator used in thepresent invention include water-soluble oxidizing agents. Examples ofthe water-soluble oxidizing agents include a peroxide such as hydrogenperoxide, benzoyl peroxide, cumene hydroperoxide, etc.; an alkali metalpersulfate such as potassium persulfate, sodium persulfate, etc.;ammonium persulfate, alkyl hydroperoxides, etc. These oxidizing agentsmay be used singly or in combination of two or more of them.

The oxidizing agent is generally used in an amount of from 0.000001 to 3g, preferably from 0.00001 to 1 g, and more preferably from 0.00001 to0.5 g, per mol of the monomer component (A).

Examples of reducing agents of the redox polymerization initiator usedin the present invention include an alkali metal sulfite, an alkalimetal bisulfite, ammonium sulfite, ammonium bisulfite, ascorbic acid,erythorbic acid, etc., and one, or two or more of these agents can beused. Particularly preferred reducing agents are ascorbic acid anderythorbic acid which makes it possible to start the polymerization at atemperature in the range of from 0° C. to 30° C. in combination with anoxidizing agent.

The reducing agent is generally used in an amount of from 0.000001 to 1g, preferably from 0.00001 to 0.1 g, and more preferably from 0.00001 to0.01, per mol of the monomer component (A).

In the present invention, a thermal polymerization initiator can be useddepending upon the selected reaction temperature and the type of theselected monomer component (A). The thermal polymerization initiator ispreferably soluble in water or the aqueous solution (D) containing themonomer component (A), the compound (B) and the compound (C). Examplesof the thermal polymerization initiator include azo initiators such as2,2-azobis-amidinopropane dihydrochloride, 4,4-butylazo-cyanovalericacid, and 2,2′-azobis(isobutylonitrile). These thermal polymerizationinitiators can be used singly or in combination of two or more of themtogether with the redox polymerization initiator if desired. Preferredthermal polymerization initiators include 2,2′-azobis-amidinopropanedihydrochloride.

The thermal polymerization initiator used in the present invention ispreferably used in an amount of from 0.00001 to 10 g, preferably, from0.001 to 1 g, per mol of the monomer component (A).

It is possible to use an appropriate combination of the redoxpolymerization initiator and the thermal polymerization initiator bytaking the reactivity of these initiators into consideration. The mostpreferred combination is that of hydrogen peroxide, ascorbic acid,sodium persulfate, and 2,2-azobis-amidinopropane dihydrochloride becausethis combination exhibits excellent polymerization initiating functionand polymerizability at a low temperature, resulting in awater-absorbing resin having a small amount of water-soluble content.

The total amount of these polymerization initiators used is generally inthe range of from 0.000001 to 10 g, preferably from 0.00001 to 5 g, andmore preferably from 0.001 to 1 g, per mol of the monomer component (A).

A conventionally known process for initiating the polymerization may beused in combination with the process for initiating the polymerizationaccording to the present invention, as long as the polymerization isinitiated with a redox polymerization initiator. Examples of such aprocess include a process of radiation with a radioactive ray, anelectron beam, a ultraviolet ray, etc.

The polymerization initiating temperature in the process for producing awater-absorbing resin according to the present invention may differdepending upon the type of initiators used. The polymerization isgenerally initiated at a temperature in the range of from 0° to 30° C.,preferably from 0° to 20° C. At a temperature below 0° C., a long periodof time may be required before initiating the polymerization. At atemperature higher than 30° C., a basic molecular weight of theresulting water-absorbing resin tends to decrease and the amount of awater-soluble content in the resin tends to increase.

In the process of the present invention, the maximum reactiontemperature is in the range of from 60° to 100° C. The term “maximumreaction temperature” as used herein means a maximum temperature of thereaction system reached by generating polymerization heat. If themaximum reaction temperature is lower than 60° C., a large amount ofmonomers remains unreacted. If the maximum reaction temperature ishigher than 100° C., the reaction cannot be controlled due to boilingduring the reaction and an amount of water-soluble content in theresulting water-absorbing resin increases.

A polymerization vessel used for polymerizing the aqueous solution (D)used in the present invention is not particularly limited. When theaqueous solution (D) is polymerized in a vessel having a plurality ofrevolving stirrer shaft, a vessel which is capable of providing ashearing force which is capable of finely dividing the hydrogel producedas a result of the polymerization by rotation of the revolving stirrershaft is preferred since the maximum reaction temperature can be easilycontrolled by removing the heat. As such vessels, a double-arm kneaderis particularly preferred. The blade equipped with revolving stirrershaft of the double-arm kneader which can be used include a sigma type,an S type, a Banbury type, a fish-tail type, a masticator type, etc.

In the process of the present invention, the concentration of themonomer component (A) in the aqueous solution (D) containing the monomercomponent (A), the compound (B) and the compound (C) is not particularlylimited, but, in consideration of easiness for controlling thepolymerization reaction and the economy, the concentration of themonomer component (A) is preferably in the range of from 15 to 70% byweight, more preferably in the range of from 20 to 50% by weight.

The aqueous solution (D) used in the present invention may, if desired,contain other monomers than the monomer component (A). These monomers isnot particularly limited, but those which are water-soluble and/orsoluble in unsaturated carboxylic acids are preferred.

Examples of other monomers include (meth)acrylic acid esters such ashydroxyethyl (meth)acrylate, methoxyethyl (meth)acrylate, hydroxypropyl(meth)acrylate, polyethylene glycol mono(meth)acrylate, polypropyleneglycol mono(meth)acrylate, methoxy polyethylene glycolmono(meth)acrylate, methoxy polypropylene glycol mono(meth)acrylate,methyl (meth)acrylate and ethyl (meth)acrylate; unsaturated sulfonicacids and salts thereof such as 2-acrylamido-2-methylpropanesulfonicacid, vinylsulfonic acid, (meth)acrylsulfonic acid, styrenesulfonicacid, sulfoethyl (meth)acrylate, sulfopropyl (meth)acrylate andvinyltoluenesulfonic acid; unsaturated amine compounds and salts thereofsuch as N,N-dimethylaminoethyl (meth)acrylate and N,N-diethylaminoethyl(meth)acrylate; unsaturated amides such as (meth)acrylamide, N-hexyl(meth)acrylamide, N-methylol (meth)acrylamide and N,N-dimethyl(meth)acrylamide; styrene or derivatives thereof such as styrene,-methylstyrene, o-methylstyrene and p-methylstyrene; (meth)acrylonitrileand vinyl acetate. These monomers may be used singly or in combinationof two or more of them. These monomers may be used, if desired, in anamount of 50% by weight or less, preferably 40% by weight or less, basedon the amount of the monomer component (A).

Various polymerization systems can be employed in the process forproducing the water-absorbing resin according to the present invention,and conventional methods for obtaining water-absorbing resins such as areverse phase suspension polymerization method, an aqueous solutionpolymerization method, and a spray polymerization method can be used. Anaqueous solution of monomers supported on a fibrous substrate can bepolymerized. A preferred method is an aqueous solution polymerizationmethod, and, in particular, a method for polymerization while finelydividing a hydrogel by shearing force is preferred from the standpointof removal of heat.

As solvents for the polymerization used in the present invention, theuse of only water is preferred, but, if necessary, a hydrophilic organicsolvent such as methanol, ethanol, isopropanol, acetone,dimethylformamide and dimethyl sulfoxide may be added to water. Further,a chelating agent may be added to water.

The water-absorbing resin obtained by the process according to thepresent invention may be used as an absorbent, a water-retention agent,etc. in the form of a hydrogel. When removal of water by drying ispreferred from the standpoint of handling, it may be used afterappropriate drying. In this case, the water content of thewater-absorbing absorbing resin is generally 70% or less, preferably 10%or less. The drying temperature can be in the range of from 90° to 250°C., preferably 100° to 180° C. An ordinary dryer, such as a hot airdryer, a reduced pressure dryer, etc. can be used. A drying temperatureof 90° C. or below may not be economical since, for example, a highdegree of reduced pressure is required for improving the productivity. Adrying temperature of 250° C. or above may cause discoloration, etc. ofthe water-absorbing resin.

The water-absorbing resin obtained after drying in the above manner isused as it is in the form of coarse particles, or in the form of powderby pulverization.

If necessary, the water-absorbing resin obtained by the process of thepresent invention may be secondarily crosslinked on the surface thereofby a polyhydric alcohol, a polyvalent epoxy compound, a polyvalentglycidyl compound, a polyvalent azilidine compound, a polyvalent aminecompound, a polyvalent isocyanate compound, a glyoxal, a polyvalentmetal salt, a silane coupling agent, an alkylene carbonate, etc. Thesecondary crosslinking may be carried out at least one occasionsselected from before drying, simultaneously with drying, and afterdrying.

The water-absorbing resin obtained by the process of the presentinvention may contain inorganic fine particles such as titanium oxide,silicon oxide and activated carbon; organic fine particles such aspolymethyl methacrylate; hydrophilic fibers such as pulp; syntheticfibers such as a polyethylene fiber and a polypropylene fiber; etc.which are added during the production steps or after the production ofthe resin.

The present invention also relates to a water-absorbing resin.

The water-absorbing resin of the present invention has a degree ofreduction in absorption magnification of from 1 to 16, and an absorptionmagnification under pressure of from 20 to 40.

A water-absorbing resin having a degree of reduction in absorptionmagnification of more than 16 drains an electrolytic solution that hasbeen once absorbed with the lapse of time, and therefore is notpreferred since it results in practical problems. For example, if awater-absorbing resin having such a high degree of reduction inabsorption magnification is used in a diaper, urine that has been onceabsorbed is drained from the water-absorbing resin with the lapse oftime, which will give an unpleasant feeling to a person using thediaper, or will cause leakage of urine since no further urine isabsorbed by the water-absorbing resin.

A water-absorbing resin having a degree of reduction in absorptionmagnification is less than 1, particularly a water-absorbing resinhaving an absorption magnification after 3 hours larger than that after10 minutes, is not preferred because it generally has a low absorbingrate and thus requires a long period of time until it reaches thesaturated absorption.

The degree of reduction in absorption magnification of thewater-absorbing resin of the present invention is preferably from 1 to12.

A water-absorbing resin having an absorption magnification underpressure of less than 20 is not preferred because the absorbingproperties of such a water-absorbing resin is deteriorated when it isapplied to practical use, in which the water-absorbing resin used underpressure. For example, if a water-absorbing resin having a lowabsorption magnification under pressure is used in a disposable diaper,the water-absorbing resin receives pressure by a person using the diaperand cannot exhibit sufficient absorbing properties, i.e., cannotsufficiently absorb urine.

The absorption magnification under pressure of the water-absorbing resinof the present invention is preferably 23 to 40.

A production process of the water-absorbing resin of the presentinvention is not particularly limited if the resulting water-absorbingresin satisfies the requirements in the degree of reduction inabsorption magnification and the absorption magnification underpressure, and any of conventional processes may be employed. Thewater-absorbing resin of the present invention is preferably produced bythe production process according to the present invention.

The present invention also relates to a water-absorbing article.

The water-absorbing article according to the present invention comprisesa water-absorbing resin having a degree of reduction in absorptionmagnification of from 1 to 16, and an absorption magnification underpressure of from 20 to 40.

The form of the water-absorbing article of the present invention is notparticularly limited and may be in the form of sheet, mass or the like.

The water-absorbing article of the present invention is not limited inother constituting components, as long as it comprises the abovewater-absorbing resin. For example, the water-absorbing article mayfurther comprise a water-permeable sheet material, a water-impermeablesheet material, crushed pulp, tissue paper, a rubber material, etc.Examples of the water-absorbing article include one in which the abovewater-absorbing resin is placed in a bag which comprises at least oneside thereof a water-permeable sheet.

The water-absorbing article of the present invention can absorb variousliquids including body fluids such as urine and blood, liquids from foodsuch as meat, fish, fruit and vegetables, ground water, brine,rainwater, etc., and thus can be applied to various products such asdiapers, sanitary goods, freshness-maintaining agents, soilwater-retaining retaining agents, sealing materials, dew condensationpreventing agents.

The water-absorbing article of the present invention is particularlypreferably applied to a disposable diaper because the degree ofreduction in absorption magnification to urine, which is an electrolyticsolution, is low, and the absorbing properties under pressure, i.e.,load of the weight of a human body, is excellent.

The present invention is further illustrated in more detail by thefollowing Examples and Comparative Examples, but the present inventionshould not be construed as being limited to these examples.

The absorption capability, the amount of water-soluble content, thedegree of reduction in absorption magnification, and the absorptionmagnification under pressure in Examples and Comparative Examples weremeasured in the following procedures.

(1) Absorption capability

Into a container having a circle bottom having a diameter of 9.5 cm, 16sheets of toilet paper each having a rectangular form of 7.5 cm×5.7 cmwere placed parallel to the bottom, and 20 g of an artificial urine I(an aqueous solution containing 1.9 wt % of urea, 0.8 wt % of sodiumchloride, 0.1 wt % of magnesium sulfate, and 0.1 wt % of calciumchloride) at 25° C. was poured into the container. A (g) (about 1 g) ofthe water-absorbing resin was placed at the center of the toilet paperand was allowed to absorb and swell for 10 minutes. The weight (B (g))of the absorbed and swollen water-absorbing resin was measured, and theabsorbing capability was calculated by the following equation:

Absorbing capability (g/g)=B(g)/A(g)

(2) Amount of water-soluble content

C (g) (about 0.5 g) of the water-absorbing resin was dispersed in 1,000g of deionized water, and, after stirring for 16 hours, the dispersionwas filtered through a filter paper and the weight of the solid contentin the filtrate was measured (D (g)). The amount of the water-solublecontent was calculated by the following equation:

Amount of water-soluble content (wt%)=(D(g)/C(g)×100

(3) Degree of reduction in absorption magnification

E (g) (about 0.2 g) of a water-absorbing resin to be measured was placeduniformly in a bag made of nonwoven cloth (40×150 mm), and immersed inan artificial urine I (an aqueous solution containing 1.9 wt % of urea,0.8 wt % of sodium chloride, 0.1 wt % of magnesium sulfate, and 0.1 wt %of calcium chloride) at 25° C. for a prescribed period of time. Afterthe bag was taken out from the artificial urine I, the artificial urineI was naturally drained for 5 second in the air and for further 10seconds on 24 sheets of toilet paper each having a rectangular form of5.0 cm×5.7 cm, and the weight (F (g)) of the bag containing thewater-absorbing resin was measured. The same procedures as above wereconducted by using the same nonwoven cloth bag but using nowater-absorbing resin, and the weight (G (g)) of the bag was measured.The absorption magnification at the prescribed period of time wascalculated by the following equation:

Absorption magnification (g/g)=(F(g)−G(g))/E(g)

The degree of reduction in absorption magnification was calculated bythe following equation:

Degree of reduction in absorption magnification (g/g)=Absorptionmagnification after 10 minutes (g/g)−Absorption magnification after 3hours (g/g)

(4) Absorption magnification under pressure

The absorption magnification under pressure was measured by using anapparatus shown in FIG. 1. An artificial urine II 3 (an aqueous solutioncontaining 2.0 0.20 wt % of potassium chloride, 2.0 0.20 wt % ofanhydrous sodium sulfate, 0.85 0.085 wt % of ammoniumdihydrogenphosphate, 0.15 0.015 wt % of ammonium dihydrogenphosphate,0.25 0.025 wt % of potassiumcalcium chloride dihydrate, and 0.5 0.05 wt% of magnesium chloride hexahydrate) at 25° C. was placed in a vessel 4equipped with an air inlet pipe 2, which was placed on a balance 1. Theinterior of the vessel 4 was connected to a reverse funnel 6 through aconnecting pipe 5. A glass filter 7 was fixed at the top of the reversefunnel 6, while the top end of the glass filter 7 and the bottom end 8of the air inlet pipe 2 were placed at the same height. A cylinder 13(inner diameter: 6.0 cm) having a stainless steel mesh bottom 12containing a water-absorbing resin 11 (0.9 g) having placed thereon aweight 10 (pressure: 0.70 psi) was placed on the glass filter 7. Theweight of the artificial urine II 3 that were absorbed by thewater-absorbing resin 11 after 60 minutes was divided by 0.9 to resultabsorption magnification under pressure (g/g).

EXAMPLE 1

A jacketed 13-liter-content stainless steel double-arm kneader equippedwith two sigma-type blades having a rotating diameter of 120 mm wascharged with 6,538 g of an aqueous solution (D) containing 2,168 g of amonomer component (A) composed of 35 mol% of acrylic acid and 65 mol% ofsodium acrylate; 24.5 g of polyethylene glycol diacrylate (an averagemolecular weight: 478) as a compound (B); 13.1 g of ethylene glycoldiglycidyl ether as a compound (C) and 4,332.4 g of deionized water. Theresulting aqueous solution (D) was degassed and the reaction system wasreplaced with a nitrogen gas.

Water at 20° C. was passed through the jacket to control the temperatureof the vessel. 12.56 g of a 10 wt% aqueous solution of2,2-azobis-2-amidinopropane dihydrochloride, 0.88 g of a 1 wt% aqueoussolution of L-ascorbic acid, 12.56 g of a 10 wt% aqueous solution ofsodium persulfate, and 5.6 g of a 0.35 wt% aqueous solution of hydrogenperoxide as initiators were added to the reaction system. The initialpolymerization temperature was controlled to 20° C. After initiation ofthe polymerization reaction, the reaction was further continued for 35minutes. During the polymerization, the revolving shaft was suitablyrotated to obtain finely divided hydrogel. The maximum reactiontemperature was 75° C. The resulting hydrogel was dried with hot air ona metal mesh at a temperature condition of 150° C. for 90 minutes. Theresulting dried material was pulverized with a hammer-mill to obtain awater-absorbing resin in the form of powder that could pass through amesh of 850 μm. The properties of the resulting water-absorbing resinare shown in Table 1.

EXAMPLE 2

A water-absorbing resin was obtained in the same manner as in Example 1except for changing the amount of ethylene glycol diglycidyl ether inExample 1 to 21.8 g. The properties of the resulting water-absorbingresin are shown in Table 1.

EXAMPLE 3

A water-absorbing resin was obtained in the same manner as in Example 1except for changing the amount of ethylene glycol diglycidyl ether inExample 1 to 4.4 g. The properties of the resulting water-absorbingresin are shown in Table 1.

EXAMPLE 4

A water-absorbing resin was obtained in the same manner as in Example 1except for changing the amounts of ethylene glycol diacrylate andethylene glycol diglycidyl ether in Example 1 to 12.3 g and 21.8 g,respectively. The properties of the resulting water-absorbing resin areshown in Table 1.

EXAMPLE 5

A water-absorbing resin was obtained in the same manner as in Example 1except for changing the amount of ethylene glycol diglycidyl ether inExample 1 to 2.2 g. The properties of the resulting water-absorbingresin are shown in Table 1.

EXAMPLE 6

A water-absorbing resin was obtained in the same manner as in Example 1except for changing the amount of polyethylene glycol diacrylate andethylene glycol diglycidyl ether in Example 1 to 12.3 g and 4.4 g,respectively. The properties of the resulting water-absorbing resin areshown in Table 1.

Comparative Example 1

A water-absorbing resin was obtained in the same manner as in Example 1except for changing the amount of polyethylene glycol diacrylate inExample 1 to 61.2 g and ethylene glycol diglycidyl ether was not used.The properties of the resulting water-absorbing resin are shown in Table1.

Comparative Example 2

A water-absorbing resin was tried to obtain in the same manner inExample 1 except that polyethylene glycol diacrylate was not used andthe amount of ethylene glycol diglycidyl ether in Example 1 was changedto 21.8 g, but dividing of the hydrogel could not proceed afterinitiation of the polymerization, and the hydrogel bumped. Theproperties of the resulting water-absorbing resin are shown in Table 1.

Comparative Example 3

A water-absorbing resin was obtained in the same manner as in Example 1except that ethylene glycol diglycidyl ether was not used. Theproperties of the resulting water-absorbing resin are shown in Table 1.

Comparative Example 4

A water-absorbing resin was tried to obtain in the same manner as inExample 1 except that L-ascorbic acid and hydrogen peroxide were notused and the amount of the 10% aqueous solution of2,2′-azobis-2-amidinopropane dihydrochloride in Example 1 was changed to25 g, but polymerization did not start.

The temperature of the jacket was then elevated to 50° C., and atemperature at which the reaction started was 46° C. The maximumreaction temperature was 115° C. The properties of the resultingwater-absorbing resin are shown in Table 1.

Comparative Example 5

A water-absorbing resin was obtained in the same manner as in Example 1except that water at 0° C. was passed through the jacket afterinitiation of the polymerization. The maximum reaction temperature was51° C. The properties of the resulting water-absorbing resin are shownin Table 1.

TABLE I Amount Amount Amount Absorp- of of of tion water- Maximum com-com- capabil- soluble reaction pound pound (B)/ ity content temperature(B)*¹ (B)*¹ (C)*² (g/g) (wt %) (° C.) Example 1 0.0020 0.0030 0.67 14.70.6 75 Example 2 0.0020 0.0050 0.40 14.4 0.5 76 Example 3 0.0020 0.00102.00 14.7 0.8 74 Example 4 0.0010 0.0060 0.20 14.1 0.4 77 Example 50.0020 0.0005 4.00 15.0 1.0 74 Example 6 0.0010 0.0010 1.00 15.0 1.2 74Comparative 0.0050 0.0000 — 15.2 1.5 77 Example 1 Comparative 0.00000.0050 0.00 14.5 3.6 110 Example 2 Comparative 0.0020 0.0000 — 15.4 2.274 Example 3 Comparative 0.0020 0.0030 0.67 14.2 5.8 115 Example 4Comparative 0.0020 0.0030 0.67 12.9 3.8 51 Example 5 Note: *¹Molar ratioto the monomer component (A) *²Molar ratio of the compound (B) to thecompound (C)

EXAMPLE 7

The water-absorbing resin obtained in Example 1 was designatedWater-absorbing resin 1; that obtained in Example 2 was designatedWater-absorbing resin 2; and that obtained in Example 3 was designatedWater-absorbing resin 3. The degree of reduction in absorptionmagnification and the absorption magnification under pressure ofWater-absorbing resins 1 to 3 were measured. The results are shown inTable 2.

Comparative Example 6

Water-absorbing resins were taken out from commercially availabledisposal diapers. A water-absorbing resin taken out from “HuggiesUltratrim Step 3” made by Kimbary Clerk was designated Water-absorbingresin 4; and that taken out from “Pampers Phases Walker 2” made by P & Gwas designated Water-absorbing resin 5. The degree of reduction inabsorption magnification and the absorption magnification under pressureof Water-absorbing resins 4 and 5 were measured. The results are shownin Table 2.

Comparative Example 7

A water-absorbing resin for waterproofing material for cables wasproduced in the manner described in Example 1 of JP-A-4-363383. A 500-mlcylindrical separable flask was charged with 31.3 g of sodium acrylate,55.2 g of acrylic amide, 0.12 g of N,N-methylenebisacrylic amide, and164.9 g of water, to produce a uniform solution.

After replacing the reaction system by nitrogen, the flask was heated to25° C. over a water bath, and then 1.94 g of a 20% aqueous solution ofsodium persulfate and 1.94 g of a 2% aqueous solution of L-ascorbic acidwere added thereto, to initiate polymerization without stirring. Thereaction system generated heat after starting the polymerization, andthe temperature of the reaction system was increased to 90° C. after 40minutes. After the increase of the temperature was stopped, thetemperature of the water bath was increased to 90° C., and the reactionsystem was aged for 40 minutes. The resulting polymer was divided intosmall pieces, dried at 160° C. for 3 hours, and then crushed to obtain awater-absorbing resin, which was designated Water-absorbing resin 6. Thedegree of reduction in absorption magnification and the absorptionmagnification under pressure of Water-absorbing resin 6 were measured.The results are shown in Table 2.

TABLE 2 Absorption Absorption Degree of magnifi- magnifi- reductioncation cation in adsorption under after magnification pressure 10minutes (g/g) (g/g) (g/g) Example 7 Water absorbing resin 1 10.8 29.520.5 Water absorbing resin 2 9.3 26.3 18.6 Water absorbing resin 3 14.825.6 24.8 Comparative Example 6 Water absorbing resin 4 16.6 8.6 26.6Water absorbing resin 5 18.4 29.7 27.7 Comparative Example 7 Waterabsorbing resin 6 −1.1 5.1 23.7

EXAMPLE 8

Water-absorbing articles were prepared by using Water-absorbing resins 1to 3. An artificial urine was poured onto the water-absorbing article,and after the prescribed period of time, the touch feeling of thewater-absorbing articles was examined.

The water-absorbing articles were prepared in the following manner:(300/(absorption magnification after 10 minutes)) g of thewater-absorbing resin and 10 g of crushed pulp was mixed in a mixer in adry condition. A web (10 cm×30 cm) was prepared from the resultingmixture by using a batch-type air-web-manufacturer. The resulting webwas sandwiched with two sheets of tissue paper having a unit weight of0.001 g/cm² and then pressed to produce a water-absorbing articleaccording to the present invention.

100 g of the artificial urine I at 25° C. was poured onto the center ofthe water-absorbing article, and a load of 0.3 psi was placed on thewater-absorbing article. After the prescribed period of time, the loadwas removed, and the touch feeling of the water-absorbing article wasexamined by a panel composed of 10 persons. The evaluation was decidedby majority to the following three grades:

A: Dry state

B: Moist state

C: Wet state

The hand feeling of the water-absorbing articles using Water-absorbingresins 1 to 3 after 10 minutes or 3 hours was examined. The results areshown in Table 3.

Comparative Example 8

The hand feeling of the water-absorbing articles using Water-absorbingresins 4 to 6 after 10 minutes or 3 hours was examined in the samemanner as in Example 8. The results are shown in Table 3.

TABLE 3 Touch feeling Touch feeling after 10 minutes after 3 hoursExample 8 Water absorbing resin 1 A A Water absorbing resin 2 A A Waterabsorbing resin 3 A B Comparative Example 8 Water absorbing resin 4 C CWater absorbing resin 5 A C Water absorbing resin 6 C C

The water-absorbing resin obtained by the process of the presentinvention has a sufficient absorption capability and a small amount ofwater-soluble content, resulting in a high safety. When thewater-absorbing resin obtained by the process of the present inventionis used as an absorbent in absorbing articles such as diapers orsanitary goods, products having a good absorbing properties can beprovided.

The water-absorbing resin of the present invention has a small amount ofwater-soluble content, a high salt resistance, and excellent absorbingproperties under pressure. The water-absorbing resin of the presentinvention having a low degree of reduction in absorption magnificationand a high absorption magnification under pressure can retain anelectrolytic solution once absorbed, and the absorption can be carriedout under pressure. For example, disposable diapers, soilwater-retaining agents, and sealing materials for brine require toabsorb and retain an electrolytic solution under pressure, and thereforethe water-absorbing resin of the present invention having a low degreeof reduction in absorption magnification and a high absorptionmagnification under pressure can advantageously used for these purposes.

The water-absorbing article of the present invention is excellent inabsorbing properties to an electrolytic solution. The water-absorbingarticle of the present invention has a reduced change in absorbingproperties after absorption, which has been a problem in coventionalwater-absorbing articles. When the water-absorbing article is applied toa diaper, the diaper is of good feeling upon use since the absorbingproperties do not change after absorbing an electrolytic solution suchas urine.

While the invention has been described in detail and with reference tospecific examples thereof, it will be apparent to one skilled in the artthat various changes and modifications can be made therein withoutdeparting from the spirit and scope thereof.

What is claimed is:
 1. A water-absorbing resin having a degree ofreduction in absorption magnification of from 1 to 16, and an absorptionmagnification under pressure of from 20 to
 40. 2. A water-absorbingresin having a degree of reduction in absorption magnification of from 1to 16, and an absorption magnification under pressure of from 20 to 40,said water-absorption resin being produced by a process, which comprisespolymerizing (D) an aqueous solution comprising (A) at least one monomercomponent selected from the group consisting of an unsaturatedcarboxylic acid and salts thereof; (B) a compound having two or moreunsaturated groups in a molecule and being capable of polymerizing byreacting with the unsaturated bonds in monomer component (A); and (C) acompound having zero or one unsaturated group which is capable ofpolymerizing by reacting With the unsaturated bonds in monomer component(A) and having two or more functional groups which are capable ofreacting with carboxyl groups in a molecule, said polymerization beingconducted in such a manner that the following conditions (a) to (c) aresimultaneously satisfied: (a) the molar ratio (B)/(C) being in the rangeof from 2×10⁻³, (b) said polymerization being initiated by a redoxpolymerization initiator, and (c) the maximum reaction temperature beingin the range of from 60° to 100° C.
 3. A water-absorbing resin asclaimed in claim 2, wherein said water-absorbing resin comprises arepeating unit derived from (A) at least one monomer component selectedfrom the group consisting of an unsaturated carboxylic acid and saltsthereof; a repeating unit derived from (B) a compound having two or moreunsaturated groups in a molecule and being capable of polymerizing byreacting with the unsaturated bonds in monomer component (A); and arepeating unit derived from (C) a compound having zero or oneunsaturated group which is capable of polymerizing by reacting with theunsaturated bonds in monomer component (A) and having two or morefunctional groups which are capable of reacting with carboxyl groups ina molecule.
 4. A water-absorbing resin as claimed in claim 2, whereinsaid water-absorbing resin comprises a repeating unit derived from (A)at least one monomer component selected from the group consisting of anunsaturated carboxylic acid and salts thereof; a repeating unit derivedfrom (B) a compound having two or more unsaturated groups in a moleculeand being capable of polymerizing by reacting with the unsaturated bondsin monomer component (A); and a repeating unit derived from (C) acompound having zero or one unsaturated group which is capable ofpolymerizing by reacting with the unsaturated bonds in monomer component(A) and having two or more functional groups which are capable ofreacting with carboxyl groups in a molecule.
 5. A water-absorbing resinas claimed in claim 2, wherein the molar ratio (B)/(A) is in the rangeof from 1×10⁻⁴ to 3×10⁻³.
 6. A water-absorbing resin as claimed in claim2, wherein the molar ratio (C)/(A) is in the range of from 5×10⁻⁵ to1×10⁻².
 7. A water-absorbing resin as claimed in claim 2, wherein saidpolymerization is conducted in such a manner that the followingconditions (d) to (f) are simultaneously satisfied: (d) the molar ratio(B)/(C) being in the range of from 0.01 to 30, (e) the molar ratio(B)/(A) being in the range of from 1×10⁻⁴ to 3×10⁻³, and (f) the molarratio (C)/(A) being in the range of from 1×10⁻⁴ to 1×10⁻².
 8. Awater-absorbing resin as claimed in any one of claims 2 and 5 to 7,wherein said functional group capable of reacting with a carboxyl groupin (C) is an epoxyl group.
 9. A water-absorbing resin as claimed in anyone of claims 2 and 5 to 7, wherein said monomer component (A) is atleast one selected from the group consisting of acrylic acid and analkali metal salt thereof.
 10. A water-absorbing resin as claimed in anyone of claims 2 and 5 to 7, wherein said redox polymerization initiatoris an initiator system comprising a reducing agent selected from thegroup consisting of ascorbic acid, erythorbic acid, and metallic saltsof these.
 11. A water-absorbing resin as claimed in claim 10, whereinsaid polymerization is initiated at a temperature in the range of from0° to 30° C.
 12. A water-absorbing resin as claimed in claim 2, whereinthe process further comprising drying after said polymerization.
 13. Awater-absorbing resin as claimed in claim 12, wherein said drying isconducted at a temperature in the range of from 90° to 250° C.
 14. Awater-absorbing resin as claimed in any one of claims 2, 5 to 7, and 12,wherein said polymerization of (D) is a radical aqueous polymerizationconducted in a vessel capable of finely dividing a hydrogel produced asa result of said polymerization by a shearing force caused by revolutionof a plurality of revolving stirring shaft.
 15. A water-absorbing resinas claimed in claim 14, wherein said vessel is a double-arm kneader. 16.A water-absorbing article comprising a water-absorbing resin having adegree of reduction in absorption magnification of from 1 to 16, and anabsorption magnification under pressure of from 20 to
 40. 17. Awater-absorbing article as claimed in claim 16, wherein saidwater-absorbing article is a diaper.
 18. A water-absorbing articlecomprising a water-absorbing resin having a degree of reduction inabsorption magnification of from 1 to 16, and an absorptionmagnification under pressure of from 20 to 40, said water-absorptionresin being produced by a process, which comprises polymerizing (D) anaqueous solution comprising (A) at least one monomer component selectedfrom the group consisting of an unsaturated carboxylic acid and saltsthereof; (B) a compound having two or more unsaturated groups in amolecule and being capable of polymerizing by reacting with theunsaturated bonds in monomer component (A); and (C) a compound havingzero or on. unsaturated group which is capable of polymerizing byreacting with the unsaturated bonds in monomer component (A) and havingtwo or more functional groups which are capable of reacting withcarboxyl groups in a molecule, said polymerization being conducted insuch a manner that the following conditions (a) to (c) aresimultaneously satisfied: (a) the molar ratio (B)/(C) being in the rangeof from 2×10⁻³, (b) said polymerization being initiated by a redoxpolymerization initiator, and (c) the maximum reaction temperature beingin the range of from 60° to 100° C.
 19. A water-absorbing article asclaimed in claim 18, wherein said water-absorbing article is a diaper.